a) \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

_____0,2<---0,6<--------------0,3

=> \(\left\{{}\begin{matrix}\%Al=\dfrac{0,2.27}{15,6}.100\%=34,615\%\\\%Al_2O_3=\dfrac{15,6-0,2.27}{15,6}.100\%=65,385\%\end{matrix}\right.\)

b) \(n_{Al_2O_3}=\dfrac{15,6-0,2.27}{102}=0,1\left(mol\right)\)

PTHH: Al₂O₃ + 6HCl --> 2AlCl₃ + 3H₂O

______0,1--->0,6

=> n_HCl = 0,6+0,6 = 1,2(mol)

=> \(V_{dd}=\dfrac{1,2}{2}=0,6\left(l\right)\)

nH2 = 2.24/22.4 = 0.1 (mol) 

Fe + 2HCl => FeCl2 + H2 

0.1___0.2_____0.1___0.1 

mFeO =  12.8 - 0.1*56 = 7.2 (g) 

nFeO = 7.2/72 = 0.1 (mol) 

FeO + 2HCl => FeCl2 + H2O 

0.1____0.2______0.1

%Fe = 5.6/12.8 * 100% = 43.75%

%FeO = 56.25%

nHCl = 0.2 + 0.2 = 0.4 (mol) 

Vdd HCl = 0.4/0.1 = 4(l) 

nFeCl2 = 0.1 + 0.1 = 0.2 (mol) 

CM FeCl2 = 0.2/4 = 0.05 (M) 

nH2 = 2.24/22.4 = 0.1 (mol) 

Zn + 2HCl => ZnCl2 + H2 

ZnO + 2HCl => ZnCl2 + H2O 

nZn = nH2 = 0.1 (mol) 

=> mZn = 6.5 g

mZnO = 14.6 - 6.5 = 8.1 (g) 

nZnO = 0.1 (mol)  

%Zn = 6.5/14.6 * 100% = 44.52%

%ZnO = 55.48%

nHCl = 0.1*2 + 0.1*2= 0.4 (mol) 

Vdd HCl = 0.4 / 0.5 = 0.8 l 

a, Ta có: 24n_Mg + 56n_Fe = 12,8 (1)

PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo PT: \(n_{H_2}=n_{Mg}+n_{Fe}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,3\left(mol\right)\\n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,3.24=7,2\left(g\right)\\m_{Fe}=0,1.56=5,6\left(g\right)\end{matrix}\right.\)

b, \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)

\(\Rightarrow V_{HCl}=\dfrac{0,8}{2}=0,4\left(l\right)\)

c, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)

\(FeCl_2+2NaOH\rightarrow Fe\left(OH\right)_2+2NaCl\)

Theo PT: \(\left\{{}\begin{matrix}n_{Mg\left(OH\right)_2}=n_{MgCl_2}=n_{Mg}=0,3\left(mol\right)\\n_{Fe\left(OH\right)_2}=n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow m_{\downarrow}=0,3.58+0,1.90=26,4\left(g\right)\)

a. Số gam mỗi kim loại trong hỗn hợp ban đầu:

b. Thể tích dung dịch HCl 2M đã phản ứng: 0,2 lít

c. Khối lượng kết tủa thu được khi dd A tác dụng với dung dịch NaOH dư là 0,4 gam.

------------------------------------đấy

Tiếp bài của creeper nhé:

c. Ta có: \(n_{ZnO}=\dfrac{4,86}{81}=0,06\left(mol\right)\)

Theo PT₍₁₎: \(n_{HCl}=2.n_{ZnO}=2.0,06=0,12\left(mol\right)\)

Theo PT₍₂₎: \(n_{HCl}=2.n_{Zn}=2.0,1=0,2\left(mol\right)\)

=> \(n_{HCl}=0,12+0,2=0,32\left(mol\right)\)

=> \(m_{HCl}=0,32.36,5=11,68\left(g\right)\)

Ta có: \(C_{\%_{HCl}}=\dfrac{11,68}{m_{dd_{HCl}}}.100\%=12\%\)

=> \(m_{dd_{HCl}}=\dfrac{292}{3}\left(g\right)\)

Theo đề, ta có: 

\(D=\dfrac{\dfrac{292}{3}}{V_{dd_{HCl}}}=1,2\)(g/ml)

=> \(V_{dd_{HCl}}=81,1\left(ml\right)\)

a)

$Fe + 2HCl \to FeCl_2 + H_2$
$FeO + 2HCl \to FeCl_2 + H_2O$

b)

Theo PTHH : $n_{Fe} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$m_{Fe} = 0,15.56 = 8,4(gam)$
$m_{FeO} = 12 - 8,4 = 3,6(gam)$

$n_{FeO} =0,05(mol)$
Theo PTHH : $n_{HCl} = 2n_{Fe} + 2n_{FeO} = 0,4(mol)$

$V_{dd\ HCl} = \dfrac{0,4}{2} = 0,2(lít)$

c) $Fe + CuSO_4 \to FeSO_4 + Cu$

$n_{Cu} = n_{Fe} = 0,15(mol) \Rightarrow m_{chất\ rắn} = m_{FeO} + m_{Cu}$

$= 3,6 + 0,15.64 = 13,2(gam)$

a,\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:     0,1     0,2         0,1            0,1

PTHH: Fe₂O₃ + 6HCl → 2FeCl₃ + 3H₂O

Mol:     0,05         0,3          0,1     

\(m_{Fe}=0,1.56=5,6\left(g\right);m_{Fe_2O_3}=13,6-5,6=8\left(g\right)\)

\(n_{Fe_2O_3}=\dfrac{8}{160}=0,05\left(mol\right)\)

b,\(m_{HCl}=\left(0,2+0,3\right).98=49\left(g\right)\)

\(m_{ddHCl}=\dfrac{49.100}{10}=490\left(g\right)\)

c,\(m_{ddX}=13,6+490-0,1.2=503,4\left(g\right)\)

d,\(C\%_{FeCl_2}=\dfrac{0,1.127.100\%}{503,4}=2,52\%\)

  \(C\%_{FeCl_3}=\dfrac{0,05.162,5.100\%}{503,4}=1,614\%\)

\(a.Fe+2HCl\rightarrow FeCl_2+H_2\left(1\right)\\ Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\\ n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ \Rightarrow n_{Fe}=n_{H_2}=n_{FeCl_2}=0,1\left(mol\right)\\ \Rightarrow\%m_{Fe}=\dfrac{0,1.56}{13,6}.100\approx41,176\%\\ \Rightarrow\%m_{Fe_2O_3}\approx58,824\%\\ b.n_{Fe_2O_3}=\dfrac{13,6-0,1.56}{160}=0,05\left(mol\right)\\ n_{HCl}=2.n_{Fe}+6.n_{Fe_2O_3}=2.0,1+6.0,05=0,5\left(mol\right)\\ m_{ddHCl}=\dfrac{0,5.36,5.100}{10}=182,5\left(g\right)\)

\(c.m_{ddX}=m_{hh\left(Fe,Fe_2O_3\right)}+m_{ddHCl}-m_{H_2}=13,6+182,5-0,1.2=195,9\left(g\right)\\ d.n_{FeCl_3}=2.0,05=0,1\left(mol\right)\\ C\%_{ddFeCl_3}=\dfrac{0,1.162,5}{195,9}.100\approx8,295\%\\ C\%_{ddFeCl_2}=\dfrac{0,1.127}{195,9}.100\approx6,483\%\)

\(n_{H2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Pt : \(Fe+2HCl\rightarrow FeCl_2+H_2|\) 

        1        2               1           1

       0,1     0,2            0,1         0,1

     \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)

         1            6              2             3

      0,05        0,3            0,1  

a) \(n_{Fe}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

\(m_{Fe}=01,.56=5,6\left(g\right)\)

\(m_{Fe2O3}=13,6-5,6=8\left(g\right)\)

⁰/₀Fe =  \(\dfrac{5,6.100}{13,6}=41,18\)⁰/0

⁰/₀Fe₂O₃ = \(\dfrac{8.100}{13,6}=58,82\)⁰/₀

b) \(n_{HCl\left(tổng\right)}=0,2+0,3=0,5\left(mol\right)\)

⇒ \(m_{HCl}=0,5.36,5=18,25\left(g\right)\)

\(m_{ddHCl}=\dfrac{18,25.100}{10}=182,5\left(g\right)\)

c) \(n_{FeCl2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

⇒ \(m_{FeCl2}=0,1.127=12,7\left(g\right)\)

\(n_{FeCl3}=\dfrac{0,3.2}{6}=0,1\left(mol\right)\)

⇒ \(m_{FeCl3}=0,1.162,5=16,25\left(g\right)\)

d) \(m_{ddspu}=13,6+182,5-\left(0,1.2\right)=195,9\left(g\right)\)

\(C_{FeCl2}=\dfrac{12,7.100}{195,9}=6,48\)⁰/₀

\(C_{FeCl3}=\dfrac{16,25.100}{195,9}=8,3\)⁰/₀

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